Ozone Concentration Flux Eddy-Correlation Chemiluminescence Instrument

Client

Institute of Arctic and Alpine Research (INSTAAR), University of Colorado, Boulder, CO

Project Objectives

  • Design and build an instrument to measure the flux of ozone above surfaces such as the ocean, terrestrial environments, or permanent snow/arctic environments
  • The instrument must have a temporal resolution of 10 Hz and measurement accuracy of 1 ppt/sec
  • The design of this instrument is based on the eddy-correlation technique.  In this method the flux of ozone into a surface is determined by the cross correlation of the vertical velocity fluctuations and ozone concentration fluctuations above the surface.

Summary of Project and Results (Non-Confidential)

  • The fluctuating concentration of ozone was measured by detecting the photons generated by chemiluminescence of the reaction between ozone and nitric oxide (NO)
  • Designed and built the chemiluminescence reaction chamber of ozone and NO
  • Assembled a vacuum pump system to draw in ambient air and nitric oxide
  • Installed systems to control the reaction chamber pressure and reactant flowrates
  • Installed a photomultiplier tube and liquid refrigerant cooling system to cool the PMT and reduce the dark current levels
  • Installed the electronic circuitry and electrical noise reduction systems to convert photons into ozone counts per second
  • Developed a computer control system using LABVIEW to control the experiment and measure the cross-correlation of ozone counts/sec and vertical velocity fluctuation signals from an anemometer


Ozone Flux Chemiluminescence Instrument